Mark's gas-liquid photoflow paper drops on ChemRxiv! We hope it finds a good home.. \(^(I)^)/
It describes an attractive method for the late-stage, selective N-CH3 oxidation of complex trialkylamines - including natural products and active pharmaceutical ingredients - using simple molecular oxygen and light! The microfluidic chip reactor safely handled O2-enriched reaction mixture, improving mass transfer, conversion and selectivity.
Find out why our new catalyst, 'DCAS', is not only more soluble than its parent DCA, but totally inverts the reaction mechanism from electron transfer to energy transfer...
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