In ChemCatChem
Photoredox catalysis: How naïve are the mechanisms we see? In this hybrid review, we exemplify with 5 different organophotocatalyst families how excited state pathways are profoundly overturned by pre-redox modifications and changes in aggregation state / catalyst-substrate preassemblies.
Aggregation effects can no longer be ignored!!!
Congrats to Mark and Jas for the outstanding and well-structured manuscript, as well as the supporting calculations!
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