After a long peer-review, AK Bärham emerge victorious with the publication of their independent study on triarylamines as tunable, precomplexing, super-oxidizing, Kasha rule-breaking electroactivated PhotoCatalysts! Check it out in Org. Chem. Front. (open access!)
We think that photocatalyst-substrate precomplexation marks the next evolutionary stage in PhotoRedox Catalysis - overturning conventional selectivities and breaking established rules in photochemistry.
Concepts in this manuscript are highly contraversial. *Proceed with caution* You have been warned ;-)
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